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31.
We investigated the partitioning of trace substances during the phase transition from supercooled to mixed-phase cloud induced by artificial seeding. Simultaneous determination of the concentrations of H2O2, NH3 and black carbon (BC) in both condensed and interstitial phases with high time resolution showed that the three species undergo different behaviour in the presence of a mixture of ice crystals and supercooled droplets. Both H2O2 and NH3 are efficiently scavenged by growing ice crystals, whereas BC stayed predominantly in the interstitial phase. In addition, the scavenging of H2O2 is driven by co-condensation with water vapour onto ice crystals while NH3 uptake into the ice phase is more efficient than co-condensation alone. The high solubility of NH4+ in the ice could explain this result. Finally, it appears that the H2O2–SO2 reaction is very slow in the ice phase with respect to the liquid phase. Our results are directly applicable for clouds undergoing limited riming.  相似文献   
32.
Direct effects of pure humic substance (BS1 FA) on three different aquatic organisms (Ceratophyllum demersum, Dreissena polymorpha, and Chaetogammarus ischnus) were demonstrated in this study. Exposure to environmentally relevant concentrations (0.5 mg/L) of this humic substance led to the activation of the microsomal and soluble glutathione S‐transferase (GST) in Ceratophyllum demersum. Exposure to 3‐chlorobiphenyl showed also an elevation of GST activity, which is due to the proposed detoxication metabolism of these chlorinated biphenyl. Coexposure to a mixture of 3‐chlorobiphenyl and BS1 FA showed a reduction of enzyme elevation, but still significant over an untreated control. The direct impact of humic substances seems not to be restricted to a specific class of organisms.  相似文献   
33.
Zusammenfassung Auswirkungen der saalischen Phase sind nun auch im Stockheimer Becken erstmals festgestellt. In der Hauptsache ist in diesem Gebiet jedoch mit orogenetischen Bewegungen im Unterrotliegenden selbst zu rechnen. — Der Vulkanismus entwickelte sich im Becken bzw. an seinen Rändern vermutlich bereits im jüngsten Oberkarbon (1. Phase, am stärksten ausgebildet) und hält dann im Unterrotliegenden an (2. Phase, evtl. noch Gehrener Stufe). Aus dem mittleren Rotliegenden sind bisher nur Porphyr-Fanglomerate angeführt worden. Allerdings muß berücksichtigt werden, daß deren Neubearbeitung noch nicht abgeschlossen ist und das Stockheimer Becken ohnehin nur einen kleinen Ausschnitt aus der Gesamtentwicklung am Südwestrand des Frankenwaldes darstellt. Mit einem Vulkanismus im mittleren Rotliegenden (3. Phase, ? Goldlauterer Stufe) ist demnach auch hier noch zu rechnen.  相似文献   
34.
The occurrence of earthquakes causing damage in regions, where no seismic activity had been observed previously, has confirmed the suspicion that the construction of high dams and pumped storage hydroelectric plants as well as the pressing of fluid into petroleum reservoirs and of waste water into deep boreholes will trigger the release of tectonic stresses in the earth's crust. A great number of examples indicates that a similar mechanism must be operative in all cases. Comparing the results of laboratory experiments to seismological observations, it is evident that the causes for the “loss of internal balance” must be sought in zones of low velocity and of relatively high energy absorption within the upper part of the earth's crust.  相似文献   
35.
Dissolution rates of natural illite (Illite du Puy) were measured from Si release rates during closed system experiments at pH ranging from 1.4 to 12.4 and temperatures ranging from 5 to 50°C. Experiments performed at 4<pH<11 exhibited reactive fluid Si/Al concentration ratios that were inconsistent with stoichiometric illite dissolution likely due to secondary phase precipitation. In contrast, after an initial preferential release of aluminum relative to silicon, the reactive fluid Si/Al concentration ratio evolution was consistent with stoichiometric illite dissolution for all experiments conducted at 4>pH>11. Si release rate decreased with time during all experiments; for those experiments performed at 4>pH>11 this observation can be attributed to either 1) changing reactive surface area; 2) the effect of initial fine particle dissolution; or 3) a negative order of the illite dissolution reaction with respect to aqueous Al and/or Si. Measured dissolution rates exhibited a typical variation with pH; rates decrease with increasing pH at acid conditions, minimize at near to neutral pH and increase with increasing pH at basic conditions. An empirical expression describing rates obtained in the present study is given by
  相似文献   
36.
Analyses of aircraft observations of the stratocumulus-topped boundary layer during the First ISCCP (International Satellite Cloud Climatology Project) Regional Experiment (FIRE I) show the frequent presence of clear, but relatively moist, air patches near the stratocumulus cloud-top interface. A conditional sampling of measurements in these clear air patches shows that their thermodynamic properties do more resemble boundary-layer air characteristics than those of free troposphere air. From an aircraft leg through cloud tops it is demonstrated that turbulent mixing across the cloud-top interface can lead to the local dissipation of the cloud top. Analogous to the terminology used for shallow cumulus parameterizations this process can be considered as detrainment, with which we mean that after a mixing event across the cloud-top boundaries, mixed unsaturated parcels become part of the clear environment of the cloud.  相似文献   
37.
High resolution 3-cm weather radar was used to observe the three dimensional structure of a weak echo region of a severe convective storm in northern Minnesota, U.S.A. Observations show that a seemingly steady-state updraft in the lower portion of the storm broke into an unsteady structure in the upper levels. This is interpreted as indicating that precipitation loading gradually decelerated the upper reaches of the updraft, resulting in periodic breakout of a new updraft core on the inflow side. This periodic behavior of the updraft may be related to hailstreaks and what has been termed the multi-celled storm.  相似文献   
38.
Variations in clay mineral composition of sediment cores from the margin and continental slope of the Sunda Shelf (southern South China Sea, SE Asia) covering the past 17,000 yr reflect changing influences of sediment sources together with clay mineral partitioning processes in shallow waters. We identify the deglacial sea level rise as the principal factor driving these changes. During the late glacial, high values of kaolinite are interpreted to reflect a higher contribution of clays from soils that have formed on the exposed Sunda Shelf and in the southern archipelagos of Indonesia. At this time core sites were located in close proximity to the mouths of the Sunda Shelf palaeo-drainage systems on the emerged shelf (“Sundaland”). The progressive landward displacement of the coastline and breakdown of these vast drainage systems during deglaciation led to a decrease in influence of the kaolinite-rich southern sources. When the coastline had retreated closely to its present-day position in mid-Holocene times, the former dominance of southern sources was replaced by a stronger influence of illite-rich sources (e.g. Borneo). The overriding control of sea level changes on the clay mineral distribution patterns precludes a definite climatic interpretation of clay mineral data in terms of climatic/monsoonal changes in such highly dynamic sedimentary environment.  相似文献   
39.
In this paper we report about a small region on the northern scarp of Olympus Mons showing an increase of the 3 μm hydration band in the OMEGA spectra, together with low superficial temperatures. Although water ice clouds can occurs on the flank of big martian volcanoes, radiative transfer modeling indicates that atmospheric water ice alone cannot justify the shape of the observed band. A fit of the 1.9–3 μm absorption features is obtained by hypothesizing that the study region consists of a mixture of dust and water ice covered by an optically thin (τ=0.08 at 3 μm) layer of dust. Thermal modeling also suggests that water ice in this region may be stable during most of the martian year due to the saturation of the atmosphere. If water ice is responsible for the observed spectral behavior, it might consist of a number of ice or snow patches possibly deposited in small depressions.  相似文献   
40.
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